1 / 29

PRESENTATION OF THE NATIONAL Institute for Research and physico- chemical analysis INRAP

e- age December 12-13/2013. Institut National de Recherche et d’Analyse Physicochimique. PRESENTATION OF THE NATIONAL Institute for Research and physico- chemical analysis INRAP Pr. NaJOUA Kamoun Turki GENERAL diRECTOR. PrEsentation OF INRAP.

ginger-neal
Download Presentation

PRESENTATION OF THE NATIONAL Institute for Research and physico- chemical analysis INRAP

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. e-ageDecember 12-13/2013 Institut National de Recherche et d’Analyse Physicochimique PRESENTATION OF THE NATIONAL Institute for Research and physico-chemicalanalysis INRAP Pr. NaJOUAKamounTurki GENERAL diRECTOR

  2. PrEsentation OF INRAP Institut National de Recherche et d’Analyse Physicochimique Pr NajouaKamounTurki General Director of INRAP • INRAP: was created by the law n°95-4 of january 1995.its specify in his section 2 the mission of the institute: • Develop and organize analytical tools in the country. • Provide to company, technical and scientific institution the means for performance, research, development and training in the field of physico-chemical analysis. e-ageDecember 12-13/2013

  3. INRAP : was designed to be • A documentation center in terms of physico-chemical analysis. • A technical service center: maintain and repair scientific equipement used by INRAP,assistance to other agencies, implementation of specific arrangements. • An institute of research and development • A training center Researche Analysis INRAP constitutive Documentation Maintenance Training e-ageDecember 12-13/2013

  4. Human ,Materieland logistical device INRAP has 170 public function workers Total area of 3Hawich 6000 m²of covered area Scientific equipment with an estimated value of 15 MD

  5. Analytical equipments of INRAP e-ageDecember 12-13/2013 Separation technique Inorganique elemental analysis Atomic absorption spectrometry (AAS) Liquid chromatography (HPLC) Gaz chromatography (GC) Atomic emission spectrometry (ICP-OES) Mass spectrometry LC-MS-MS GC-HRMS GC-MS

  6. Analytical equipments of INRAP e-ageDecember 12-13/2013 Infrared Fourrier transform X fluoressence UV-Visible spectroscopy environnemental scaning electron microscopy Thermal analysis ATD ATG DSC

  7. Analyticalequipments of INRAP X ray diffraction Organic elemental analysis CHNOS Ionic chromatography Water analysisKarl Fisher, Spectrophotometry (Na, K, Ca), DCO, DBO5, Turbidity…)

  8. e-ageDecember 12-13/2013 Analyticalequipments of INRAP GC-MS-MS NMR 500 MHz LC-MS-MS

  9. P1 Watch Normative LMTA: Laboratory of Analytical and technicalmethod Researchproject Active contribution to the adoption of international standards and adapt to national needs P2 Métrology - Establishing a connection string pH measurement and a primary reference bench pH measurement. - Certification of buffer solution P3 Tools and methods of analysis e-ageDecember 12-13/2013

  10. Ministère de l’Enseignement Supérieur, et de la recherche scientifique Institut National de Recherche et d’Analyse Physico-chimique USEFUL MATERIALS LABORATORY • 2 Research programs • Nano-structuredMaterials • Hydrides and metalcarbidesnanomaterials • Oxidenanomaterials: A patent is already granted • 2) Valuation of minerals and rare earths • -Characterization of minerals and rare earths • - Economicanalysis and extraction of rare earths e-ageDecember 12-13/2013

  11. Nano-structured Materials Metal hydride • Application • accumulator Ni-MH • Fuel cell Metal carbide Application : High performance cutting tools e-ageDecember 12-13/2013

  12. Laboratory of natural substances Code: LR10INRAP02 Year of creation: 2010 http://www.inrap.rnrt.tn e-ageDecember 12-13/2013 • Program n°1: Bioactive substances of natural origin • Project 1 : Physico-chemical screening of naturally occurring substances • Project 2 : Demonstration of biological and pharmaceutical activities • Program n°2: The bio-polymers and formulation • Project 1 : The eco-compatible bio-polymers • Project 2 : Formulation

  13. Synthesis and characterzation of lowcostnanomaterialsused in photovoltaicdevices Pr N. KamounTurki Director of Physics Condensed Matter e-ageDecember 12-13/2013

  14. Introduction: Renewableenergies Geothermal Photovoltaic solar energy The wind The waterfalls Plant growth e-ageDecember 12-13/2013

  15. Water bath Thermometer Substrat Deposition solution Agitator magnetic heating Atom-by-atom Aglomeration clusters Nature of substrat + Growth mode Combinaison mécanisms Experimental Conditions CBD: In2S3, ZnS, PbS, SnS, Cu2S : 5 Cot. Th, 2 CMCU: 03-09; AUF 2011-2012 Reagents and preparation of solution e-ageDecember 12-13/2013

  16. Effect of aluminum doping on the physical properties of thin films In2S3 e-ageDecember 12-13/2013

  17. Effect of Al doping (Optical properties) Transmission spectra for different concentration ratios y = ([Al] /[In])sol 60  T(%)  75, maximal transmission for y = 4% In2S3:Al/verre In2S3:Al/SnO2 It is a good value for the use of β-In2-xAlxS3 as optical windows in photovoltaic devices e-ageDecember 12-13/2013 14

  18. Effect of tin doping on the physical properties of thin films In2S3 e-ageDecember 12-13/2013

  19. Influenceof heat treatment on structural, optical and electrical properties of In2S3 chemically synthesized e-ageDecember 12-13/2013

  20. Effect of Fluorine doping on the optical and electrical properties of In2O3 elaborated for [In] = 0.04M and Ts = 500°CTuniso-Algerian Project 2012-2013 Optical transmission and reflection • Fluorine doped indium oxidethin films have a highoptical transmittance (is in order of 80%) • Eg = 3.17 eV (y=0) • Eg = 3.24 eV (F) • OPTICAL WINDOW : PV devices Electrical properties Thermally stimulated current (TSC) of In2O3 :F (2%) • TSC isalmostconstant • No trapsin the material e-ageDecember 12-13/2013

  21. Elaboration process The Spin Coating technique e-ageDecember 12-13/2013

  22. opticalproperties PhD: Wafa Naffouti • 86 < T < 89 % in Transparency range. • Eg :Transition around 2,3 eV T and R spectra of P3HT /glass for different solution concentrations • Oscillations appear: Effect of interference. e-ageDecember 12-13/2013 T and R spectra of P3HT / SnO2:F/glass for different solution concentrations

  23. EEFECT OF Ga INCORPORATION ON PHYSICAL PROPERTIES OF CuInS2 THIN FILMS SUNTHESIZED BY CHEMICAL SPRAY PYROLYSISPhDMejdaAjili e-ageDecember 12-13/2013

  24. Chemical Spray pyrolysis • a nozzle fixed on a one-dimentional moving support allowing it to pulverize the whole isothermal zone containing the cleaned substrates placed on to heated system. • The nitrogen was used as a carrier gas that serves to the pulverization of fine droplets of aqueous solution. e-ageDecember 12-13/2013

  25. Fig. Variation of (αhν)2 with photon energy (hν) of sprayed CIGSthin films at different [Ga]. For y varying from 10 to 20 at.%, Eg is in the interval [1.47-1.52] eV which is in suitable range for sunlight absorption. e-ageDecember 12-13/2013

  26. EFFEcT of SUBSTRATE TEMPERTURETs on the Structure of Cu2ZnSnS4 : CZTS Spray Z. Seboui, Y. Cuminal and N. Kamoun J. Renewable and SustainableEnergy, 5 (2013). The spectra indicate a kesterite structure of CZTS. All films are found to contain a very small peack (*) corresponding to CuxS secondary phase The best cristallinity : Ts = 280 °C The band gap energy of CZTS grown at 280 °C is in the order of 1.53 eV.

  27. Structural Analysis of SnS:In e-ageDecember 12-13/2013 transparency region weak interference fringes uniform thickness as well as smooth surfaces [1] • zinc blende structure Increase of cristallite size Eg SnS:In [1]  Eg undoped SnS [2] [1]Meriem Reghima, Anis Akkari, Michel Castagné and NajouaKamoun-Turki, journal of the Renewable and Sustainable energy, 4, 011602 (2012) [2] A. Akkari, C. Guasch, N. Kamoun-Turki; Journal of Alloys and Compounds 490 (2010) 180–183

  28. e-ageDecember 12-13/2013 The low cost solar cells’ structure Conclusion Substrate SnO2:F/ZnO:Sn/In2S3/CuInS2:Ga/Au SnO2 :F/ZnO:Sn/In2S3/Cu2ZnSnS4/Au SnO2:F/ZnO:Sn/In2S3/SnS:Cu/Au SnO2 :F/ZnO:Sn/In2S3/SnS:In/Au TZO/In2S3/CIGS SnO2:F/In2O3/In2S3/SnS:Cu/Au SnO2 :F/In2O3/In2S3/SnS:In/Au SnO2:F/In2O3:F/In2S3/CuIn(1-x)GaxS2/Au SnO2 :F/In2O3:F/In2S3/Cu2ZnSnS4/Au Absorber Contact Buffer layer opticalwindow Ohmic contact SnO2:F // Opt.W/ B.L / Absorber//Ohmic.C

  29. Thankyou for your attention e-ageDecember 12-13/2013 29

More Related