1 / 62

Organic Chemistry

Organic Chemistry. The study of carbon compounds. Organic Chemistry Introduction . Video 10.1. Organic versus Hydrocarbon. Organic molecules must have the element C. Hydrocarbons can only have the elements H and C.

vern
Download Presentation

Organic Chemistry

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript


  1. Organic Chemistry The study of carbon compounds

  2. Organic Chemistry Introduction Video 10.1

  3. Organic versus Hydrocarbon • Organic molecules must have the element C. • Hydrocarbonscan only have the elements H and C. • Therefore hydrocarbons are organic but not all organic compounds are hydrocarbons: • CH4 is a hydrocarbon and is organic • CCl4 is organic but not a hydrocarbon • O2 is neither organic nor a hydrocarbon

  4. Organic molecules • Found in fossil fuels, plants and animals. • Examples include gasoline, oil, kerosene, butane, propane…

  5. Hydrocarbon Properties • Mostly insoluble (nonpolar) • Non-electrolytes (do not conduct electricity) • React very slowly because they are covalent (nonmetals only). • As size increases, the melting point and boiling point of the hydrocarbons increase. • Small hydrocarbons may be gases and large hydrocarbons may be solids at room temperature.

  6. Carbon • Remember carbon has four valence electrons. Therefore carbon will bond four times to achieve an octet. • Each bond shown shares two electrons. One from C and one from H.

  7. Organic molecules • Sometimes double and triple bond will be needed to fulfill all octets. • A double bond shares four electrons. • A triple bond shares six electrons.

  8. Organic Molecules • All single bonded hydrocarbons are in the same family known as alkanes. • All double bonded hydrocarbons are in the same family known as alkenes. • All triple bonded hydrocarbons are in the same family known as alkynes. • Refer to table Q

  9. Organic Molecules • Notice the picture shows you the number of bonds. • Table Q also shows that if you know how many carbon atoms are present in a molecule and what type of bonds it has, you can CALCULATE the number of hydrogen atoms using the general formula. But drawing it out might be easier.

  10. Organic Molecules Table P shows your prefixes to determine how many Carbon atoms a compound has.

  11. Give the prefix for the following: Eth Prop But Pent Hex Hept Oct Non Dec • C2H6 • C3H6 • C4H6 • C5H12 • C6H12 • C7H14 • C8H18 • C9H16 • C10H20

  12. Organic Compounds • Putting P and Q together we can name simple hydrocarbons: Methane Ethene Butane Ethyne

  13. Saturation • Compounds like fats that are saturated have many hydrogen atoms. This requires single bonds. Alkanes are saturated with single bonds. • Compounds that are unsaturated have double and triple bonds, therefore, they have less hydrogen atoms. Alkenes and alkynes are unsaturated.

  14. Cyclic and Branched Hydrocarbons Video 10.2

  15. Cyclic hydrocarbons • To name them, use the prefix “cyclo”: • A four member ring is cyclobutane • A five member ring is cyclopentane • A six member ring in cyclohexane

  16. Name cyclopentyne 1,3-cyclohexadiene 1, 3, 5-cyclooctatriene

  17. benzene • An important aromatic hydrocarbon is benzene. • It has alternating double and single bonds. • It is very stable and gives off pleasant odors like cinnamon and vanilla. (“aroma”)

  18. Branched hydrocarbons • When naming branched hydrocarbons, name the longest chain and use that as the ‘last name.’ Then name the shorter chains, specifying the position of each branch. Also make sure that your branches are numbered as low as possible. 3-ethyl 1-heptene

  19. Branched hydrocarbons These are all just butane!!!

  20. Branched hydrocarbons 2 methyl hexane 2 methyl propane The little branches are known as alkyl groups which is why they have a “yl” ending.

  21. Branched hydrocarbons 2,5 dimethyl hexane

  22. 7 6 5 4 3 2 1 CH3 - CH2 - CH2 – CH – CH – CH - CH3 CH2 CH3 CH3 CH3 Find the longest continuous chain of carbons. This is the parent chain. Look at all bonds between carbons to determine type of hydrocarbon . Count from the side with the alkyl groups All single bonds so ending is… ane. There are 7 continuous carbons, so the parent chain is heptane

  23. 7 6 5 4 3 2 1 CH3 - CH2 - CH2 – CH – CH – CH - CH3 1 4 5 6 7 2 3 CH3 CH2 CH3 Number the carbons in the main sequence starting with the end that will give the alkyl groups the smallest #. CH3 • The chain is numbered from right to left because it gives the attached groups the lowest possible number

  24. 7 6 5 4 3 2 1 CH3 - CH2 - CH2 – CH – CH – CH - CH3 CH2 CH3 CH3 Add numbers to the names of the groups to identify their positions on the chain. These are prefixes with a “yl” ending. CH3 In this ex. the positions are: 4 2 - methyl, - methyl, - ethyl 3

  25. 7 6 5 4 3 2 1 CH3 - CH2 - CH2 – CH – CH – CH - CH3 CH2 CH3 CH3 Use prefixes to indicate the appearance of a group more than once in the structure. And list them in alpha order CH3 Di = Tri = = four times = five times twice threetimes Tetra Penta

  26. 7 6 5 4 3 2 1 CH3 - CH2 - CH2 – CH – CH – CH - CH3 • The name of this compound is: CH3 CH2 CH3 CH3 2,3-dimethyl– 4-ethylheptane

  27. Branched hydrocarbons 3 hexyne 3,4 diethyl octane Each angle is a carbon 3, 5, 6 trimethyl 7 ethyl decane

  28. Branched hydrocarbons 2, 3 dimethyl 4 propyl 2 heptene

  29. Other groups • More groups can be on the ring/branch such as: • F fluoro • Clchloro • Br bromo • I iodo

  30. Branched hydrocarbons 2 bromo 3 methyl butane 2 bromo 2 methyl propane 1 bromo4 methyl benzene

  31. Isomers Video 10.3

  32. Formulas C2H6 CH3CH3 • Molecular Formula: shows the number of atoms of each element in a compound. • Structural Formula: diagram of the molecular shape of a compound. • Condensed Structural Formula: each carbon is written separately followed by atoms bonded to it.

  33. isomers • Isomers have the same molecular formula but rearranged in a different structure with different properties. • Draw three isomers of butene: • Why not 3-butene? cyclobutane

  34. Circle the isomers:

  35. Benzene substitution • The benzene ring consists of 6 carbons in a ring of alternating double and single bonds. • When substituted once, just use prefixes such as methylbenzene:

  36. Benzene substitution • When the benzene is substituted twice you can number the groups: 1,2 dimethyl benzene 1,3 dimethyl benzene • Name: 1, 3 di methyl benzene!

  37. Functional groups Video 10.4

  38. TAKE OUT TABLE R!!!!!

  39. Halides • Have one of the halogens as a branched group. Names as we did in the previous lessons. 1, 2 dibromoethane

  40. Alcohol • Suffix: -ol • Flammable, soluble

  41. Ether • Name small chain, large chain, suffix: -ether • Anesthetic, soluble

  42. Aldehyde • Suffix: -al • Soluble, reactive

  43. Keytone • Suffix: -one • Somewhat soluble, needs at least 3 carbons

  44. acids • Suffix: -anoic acid • Also known as carboxylic acids: weak acids/ weak electrolytes

  45. Esters • Name chain adjacent to double bonded O last, Suffix: -anoate • Smells great (perfumes, foods)

  46. Amine Nitogen is present • Prefix: amino- • Basic, used in dyes, found in proteins: DNA

  47. Amine

More Related