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??? ???????? ??????? ?????? ????? Nano Composite Polymers
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1. ??? ???????? ???????????? ?????- ??? ?? Nano Composite Polymers
The Future is NOW
Shenkar Nano Conference 2007
2. ??? ???????? ??????? ?????? ?????Nano Composite Polymers Material of the Future
4. Nano Composite Global ConsumptionTypes of Nano % by value 2005 2011
Clay Nano-composities (NC) 24% 44%
Metal & Metal Oxide (NC) 19% 20%
Carbon Nanotubes 15% 7.5%
Ceramic Nanocomposites 11.5%
Total Global Nanocomposite consumption
Tons 10,450 43,000
Value US$ 252 million 857 million
bcc Research Nanocomposites, Nanoparticles, Nanoclays and Nanotubes Report NAN 021C June 2006
5. Nano Composites By Application Application 2005 2001
Automotive 29% 15%
Energy 28% 26%
Packaging 19% 28%
Coatings 14% 14%
Others 10% 17%
bcc Research Nanocomposites, Nanoparticles, Nanoclays and Nanotubes Report NAN 021C June 2006
6. ?????? ? Figures in Nano2002
7. ?????? - Sales
8. NANO
14. NANO SOLAR
15. NANO SYS
16. NANO TEX
17. MIT NANO
18. NANO-TECHNOLOGY One or more dimensions are in the
1 100 nano-meter (nm) range
Three main directions have been developed in nano-technology:
Nano-electronics reduction of microelectronic unit size to less than 100 nm (0.1 micron)
Nano machines functional robots of less than 1 micron
Nano-materials powders, coatings and foams in the nano-meter range
19. Nanoclays
21. Nanoclays Natural State: Dense Agglomerate
Need to separate individual platelets for maximum surface area
Optimum Performance Requires Platelets to be Exfoliated / Dispersed
22. Nanoclays Aluminosilicate minerals Montmorillonite (d=2.6)
Platelets: 200 - 600nm x 1nm
Aspect Ratio for Reinforcement
Surface Area for Impact Retention
Property Enhancement Provided by Large Surface Area / Small Particles
Low Filler levels (4% - 10%)
Isotropic Property Enhancement
Maintain Viscosity of Base Resin
24. Nanoblend Concentrates
25. ?? ???? ???? (?????) ? (?????? ????)
26. ???????? ?????? ?????? ????????Potential Improvement - Polymers
28. Full Exfoliation:Critical to Performance
30. ?????? ???-????? ? HDPE (?????)
31. ?????? ???-????? ? PP ??????
33. ??????? ApplicationsNano Composites
35. Film Applications
36. Barrier Properties of Polyolefin Nanocomposite Films
40. CO2 Shelf Life M9 also delivers a higher level of CO2 barrier.
This figure shows CO2 retention curves of bottles. The horizontal line shows storage time and the vertical line shows CO2 retention. The test bottle is 500 cc by volume, 28 grams by weight. The average wall thickness is 390 microns.
We have introduced that 5 % barrier layer of neat MXD6 extends the shelf life to double of PET monolayer. Assuming the limit of CO2 retention is 10 % off, M9 bottle has a shelf life of about 5 months.M9 also delivers a higher level of CO2 barrier.
This figure shows CO2 retention curves of bottles. The horizontal line shows storage time and the vertical line shows CO2 retention. The test bottle is 500 cc by volume, 28 grams by weight. The average wall thickness is 390 microns.
We have introduced that 5 % barrier layer of neat MXD6 extends the shelf life to double of PET monolayer. Assuming the limit of CO2 retention is 10 % off, M9 bottle has a shelf life of about 5 months.
41. Clarity
42. Effect with halogenated FR systems
45. Weight Loss of Fuel C from 22 liter Containers During 21Days (at 23o C and 50o C) HDPE lost 150 gr at 23o C
650 gr at 50o C
HDPE/Nano - no loss at 23o C
12 gr at 50o C
HDPE/fluorinated-no loss at 23o C
9 gr at 50o C
46. RIPAL ACTIVITIES IN POLYMER NANO COMPOSITES Polypropylene/Nano Clay Fire retardancy
ABS/Nano Clay Fire retardancy
HIPS/Nano Clay Fire retardancy
Nylon/Nano Clay Fire retardancy
PBT/Nano Clay Fire retardancy
EVOH/Nano Clay High barrier
PET/Nano Clay High barrier
Epoxy/Nano Clay High barrier
Engineering Plastics/Carbon Nano Tubes Reinforcement, static dissipation and conductivity
HDPE/Nano Clay High barrier containers
LDPE/Nano Clay Barrier films
55. NaturalNano Solution:
57. Future Market Opportunity
59. Future Market Opportunity
61. Companies active in Nano
64. ?????? ??????Info Sources for Presentation