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Objectives. To understand the meaning of empirical formula To learn to calculate empirical formulas To learn to calculate the molecular formula of a compound. What is the Formula?. mass spec. If I analyze a compound by mass as 7.7% Hydrogen and 92.3 % Carbon what is its formula?
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Objectives • To understand the meaning of empirical formula • To learn to calculate empirical formulas • To learn to calculate the molecular formula of a compound
What is the Formula? mass spec • If I analyze a compound by mass as 7.7% Hydrogen and 92.3 % Carbon what is its formula? • If I have 100g of the compound how many grams do I have of each element? • How many moles of each element do I have? • What is the simple number ratio between the two numbers of moles? • What is the formula? • Is this the only possible formula?
A. Empirical Formulas • The empirical formula of a compound is the simplest whole number ratio of the atoms present in the compound. • What is the empirical formula of the following compounds? • Sodium Peroxide Na2O2 • Terephthalic acid C8H6O4 • Phenobarbital C12H12N2O3 • 1,4-dichloro-2-butene C4H6Cl2
C. Calculation of Molecular Formulas • The molecular formula is the exact formula of the molecules present in a substance. • The molecular formula is always an integer multiple of the empirical formula. Molecular formula = (empirical formula)n where n is a whole number Empirical Formula: CH Molar Mass = 78 Molecular Formula?