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Writing Ionic Formulas

Writing Ionic Formulas. Chemical Formulas from Names & Names from Chemical Formulas. Basic Principles. Formulas show smallest whole-number ratio of ions (posititve and negative) in the substance.

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Writing Ionic Formulas

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  1. Writing Ionic Formulas Chemical Formulas from Names & Names from Chemical Formulas

  2. Basic Principles • Formulas show smallest whole-number ratio of ions (posititve and negative) in the substance. • Formulas are correct only if total charges of all ions add to zero (bulk matter is electrically neutral). • Cations (positive) written and named before anions.

  3. Periodic Table of the Elements

  4. +1 Periodic Table of the Elements

  5. Periodic Table of the Elements +2

  6. Periodic Table of the Elements +2 for many; some +1, others +3; several vary

  7. Periodic Table of the Elements -1

  8. Periodic Table of the Elements -2

  9. Periodic Table of the Elements -3

  10. Periodic Table of the Elements +2

  11. Periodic Table of the Elements +3

  12. Periodic Table of the Elements +2 +2 +1

  13. Periodic Table of the Elements No ions for noble gases.

  14. Combining Ions Remember: Charges must add to zero. Na+ with S2- Na+S2- Na+ Na2S Ca2+ and Cl-1 Cl-1 Ca2+ Cl-1 CaCl2 +1 -2 +2 -1 +1 -1

  15. Br-1 Br-1 Al3+ Br-1 Combining Ions Remember: Charges must add to zero. Mg+2 with S2- Mg+2S2- MgS Al3+ and Br-1 +2 -2 AlBr3 +3 -1 -1 -1

  16. Combining Ions Remember: Charges must add to zero. Mg+2 with N3- Mg+2N3- Mg+2 N3- Mg+2 Mg3N2 +2 -3 +2 -3 +2

  17. You Do One… Remember: Charges must add to zero. Ba+2 with I- I- Ba+2I- BaI2 +2 -1 -1

  18. And another… Remember: Charges must add to zero. Al3+ with F- AlF3 +3 -1 -1 -1

  19. Again… Remember: Charges must add to zero. Al3+ with O2- Al2O3 +3 -2 -2 +3 -2

  20. Transition-metal Cations • Named with positive charge as Roman numeral • +1 = (I) • +2 = (II) • +3 = (III) • Only rarely are charges bigger than three.

  21. Transition-metal Cations • Several elements can, under different conditions, form ions with different charges. • Iron is +2 or +3, Iron(II) or Iron(III) • Copper is +1 or +2, Copper(I) or Copper(II) • A given ion will have only one charge; its value depends on how the ion was formed.

  22. Combining Ions Rules are the same; charges add to zero. Chromium(III) with chloride Cr+3Cl- Cl- Cl- CrCl3 +3 -1 -1 -1

  23. Write these formulas… Silver oxide +1 -2 +1 Ag2O

  24. Write these formulas… Iron(III) iodide +3 -1 -1 -1 FeI3

  25. Write these formulas… Copper(II) oxide +2 -2 CuO

  26. Write these formulas… Copper(I) oxide +1 -2 +1 Cu2O

  27. Polyatomic Ions • Multi-atom Ions • Usually are negative • Usually contain oxygen • Names often end in -ite or -ate • Charges and formulas cannot be predicted from Periodic Table

  28. Polyatomic Ions • Nitrate = NO3-1 • One N plus three oxygens; total charge = -1 • Carbonate = CO3-2 • One carbon plus three oxygens; total charge = -2 • Sulfate = SO4-2 • One S plus four oxygens; total charge = -2 • Hypochlorite = ClO-1 • One Cl plus one oxygen; total charge = -1

  29. Good News! • Same rules for writing ionic formulas using ployatomic ions as for “simple ions” • Charges of all ions must add to zero

  30. Combining Ions Rules are the same; charges add to zero. Sodium nitrate Na+1 and NO3-1 NaNO3 +1 -1

  31. Combining Ions Rules are the same; charges add to zero. Sodium carbonate Na+1 and CO3-2 Na2CO3 +1 -2 +1

  32. Combining Ions Rules are the same; charges add to zero. Magnesium nitrate Mg+2 and NO3-1 Mg(NO3)2 +2 -1 -1 Note:where more than one polyatomic ion occurs, it must be enclosed in parentheses. A subscriptalways follows the closed parenthesis.

  33. Write these formulas… Copper(I) carbonate +1 -2 +1 Cu2CO3

  34. Write these formulas… Iron(II) nitrate +2 -1 -1 Fe(NO3)2

  35. Note, this polyatomic ion appears only once and does not have parentheses. Write these formulas… Ammonium phosphate +1 -3 +1 +1 (NH4)3PO4

  36. Names these substances... • Na2SO4 • Cu2S • FeS • Fe2S3 • FeSO4 • Mg3N2 • Mg(NO3)2 Sodium sulfate Copper(I) sulfide Iron(II) sulfide Iron(III) sulfide Iron(II) sulfate Magnesium nitride Magnesium nitrate

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