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NANOPARTICULAS MATÁLICAS QF-435-AULA-8

NANOPARTICULAS MATÁLICAS QF-435-AULA-8. Prof. Nelson Durán-IQ-UNICAMP. Chem. Eur. J. 2004, 10, 5570 – 5579. Drechsler, Erdogan, and Rotello. Elechiguerra et al. J. Nanobiotechnol. 396) 2005. METALLIC NANOPARTICLES AS CARRIERS. METALLIC NANOPARTICLES AS CARRIERS.

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NANOPARTICULAS MATÁLICAS QF-435-AULA-8

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  1. NANOPARTICULAS MATÁLICAS QF-435-AULA-8 Prof. Nelson Durán-IQ-UNICAMP

  2. Chem. Eur. J. 2004, 10, 5570 – 5579 Drechsler, Erdogan, and Rotello Elechiguerra et al. J. Nanobiotechnol. 396) 2005

  3. METALLIC NANOPARTICLES AS CARRIERS

  4. METALLIC NANOPARTICLES AS CARRIERS Lewin et al. Nat. Biotechnol. 18, 410 (2000) Gimenez et al. J. Biomed. Nanotechnol. 1, 1-7 (2005) HAuCl4 + NaHB4 Ho et al. Anal. Chem. 2004, 76, 7162-7168. Li et al. nnotechnology 2005, 16, 1912-1917

  5. Alves et al. Patente Braz. PIBr 0502657-1 (2005).

  6. Lewin et al. Nat Biotechnol. 18, 410 (2000)

  7. http://www.massmedic.com/docs/rotello.pdf

  8. http://www.massmedic.com/docs/rotello.pdf

  9. Mixed Monolayer ProtectedGold Clusters (MMPCs) http://www.massmedic.com/docs/rotello.pdf

  10. Exemplo:Np's de Au funcionalizadas com anti-câncer para Leucemia. • Preparação: • Redução de Ácido tetracloroáurico(III) com Borohidreto de Sódio. • Funcionalização após 30s da adição do agente redutor Podsiadlo et al. Langmuir. 24, 568, 2008 6-mercaptopurine

  11. PRATA EM PRODUTOS

  12. Pasta de Dente

  13. Que fazem as nanopartículas? Escova de dentes

  14. Purificador de Ar Refrigerador

  15. Que fazem as nanopartículas? Sem comentários

  16. MATERIAS PARA FERIMENTOS Área superficial grande de partículas de prata tamanho nano melhora a efetividade antibacteriana -melhora os tempos de recuperação -mata bactéria mais rápido com nanoparticulas que outras formas de prata

  17. Como preparar as nanopartícula? Nanopartículas de prata Sal do metal + agente redutor E.C. Constable, Depart. Chemistry, University of Basel, Switzerland

  18. Como preparar as nanopartícula? Nanopartículas de Au e Pd Arredondadas, lisas de 18 nm de partículas de Au por redução de citrato Hexagonal de 30 nm de partículas de Pd preparada por redução de uma sal de Pd com baixa concentração de ácido ascórbico E.C. Constable, Depart. Chemistry, University of Basel, Switzerland

  19. Como preparar as nanopartícula? Nanopartículas de metais Conhecidas da antiguidade Ouro coloidal usada para vidros tingido com vermelho e púrpura dos tempos medievais até agora E.C. Constable, Depart. Chemistry, University of Basel, Switzerland

  20. Sintese de nanoparticulas metalicas 85oC FeCl3 + 6H2O + FeCl2 . 4H2O + NH4OH -------------- HAuCl4 + NaBH4 --------------- [Ag(NH3)2]+ Ac. ascorbico/1 h r.t. --------------

  21. PREPARATION Chemical Synthesis of silver nanoparticles

  22. Como preparar nanopartículas? Nanocubos de prata E.C. Constable, Depart. Chemistry, University of Basel, Switzerland

  23. Como preparar as nanopartícula? Nanopartículas de óxidos metálicos E.C. Constable, Depart. Chemistry, University of Basel, Switzerland

  24. Caracterização de nanopartículas de TiO2 por TEM E.C. Constable, Depart. Chemistry, University of Basel, Switzerland

  25. Como caracterizar as nanopartículas?

  26. BIOSYNTHESIS OF SILVER NANOPARTICLES BY FUNGI

  27. BIOSYNTHESIS OF SILVER NANOPARTICLES BY FUNGI Fusarium oxysporum Ahmad et al. Colloids Surf. B. Biointerfaces 2003, 28, 313-318. Mukherjee et al. ChemBioChem. 2002, 3, 461-463. Pune-India Aspergillus fumigatus Bhaisa and D´Souza, Colloids Surf. B. Bio- interfaces 2006, 47, 166-164 Munbai-India

  28. BIOSYNTHESIS OF SILVER NANOPARTICLES BY FUNGI Phoma sp Chen et al. Lett. Appl. Microbiol. 2003, 37, 105-108 Beijing, China Phanerochaete chrysoporium Vigneshwaran et al. Colloids Surf. B. Biointerfaces, 2006, 53, 55-59 Munbai-India Aspergillus flavus Vigneshwaran et al. Mat. Lett. 2007, 61, 1413-1418 Munbai-India Pleurotus sajor-caju Vigneshwaran et al. Indian Pat. Appl. 2007:709864

  29. BIOSYNTHESIS OF SILVER NANOPARTICLES BY FUNGI Durán et al. J. Biomed. Nanotechnol. 2007, 3, 203-208. Campinas, SP-Brazil Fusarium oxysporum Durán et al. J. Nanobiotechnol. 2005. 3:8, 1-7. Campinas-SP-Brazil

  30. BIOSYNTHESIS OF SILVER NANOPARTICLES BY BACTERIA AND YEAST

  31. BIOSYNTHESIS OF SILVER NANOPARTICLES BY BACTERIA AND YEAST Yeast strain Kowshik et al. Nanotechnology 2003, 14, 95-100. Berlin, Germany Aeromonas sp. Fu et al. Chin.J. Chem. Eng. 2006, 14, 114-116. Xiamen, China Enterobacter clocae Shahverdi et al. Process Biochem. 2007, 42, 919-923 Teheran-Iran

  32. Bacterial Biosynthesis of Cadmium Sulfide Nanocrystals Sweeney et al. Chem. Biol. 11, 1553 ()2004)

  33. Cd S C Fe O N P

  34. Sulfeto de Cadmio assistido por Lactobacillus sp. Jha et al. NANO: Brief Reports and Reviews Vol. 2, No. 4 (2007) 239–242

  35. Biogenic formation of photoactive arsenic-sulfide nanotubes by Shewanella sp. strain HN-41. Lee et al., PNAS, 104, 20410–20415 (2007)

  36. BIOSYNTHESIS OF SILVER NANOPARTICLES BY PLANT EXTRACTS

  37. BIOSYNTHESIS OF SILVER NANOPARTICLES BY PLANT EXTRACTS Geranium (Pelargonium graveolens) Shankar et al. Biotechnol Prog. 2003, 19, 1627-1631 Pune, India Neem leaf broth Shankar et al.J. Colloid Interf. Sci. 2004, 275, 496-502. Pune,India

  38. BIOSYNTHESIS OF SILVER NANOPARTICLES BY PLANT EXTRACTS Cinnamomum camphora leaf Huang et al. Nanotechnology, 2007, 18, 1-11 Xiamen, China Alfalfa grass Gardea-Torresdey, Langmuir2003, 19, 1357-1361 Texas, USA/Mexico, Mexico Aloe vera plant extract Chandran et al., Biotechnol Prog. 2006, 22, 577-583. Pune, India Emblica Officinalis Ankamwar et al., J. Nanosc. Nanotechnol. 5, 1665-1671. Pune, India

  39. MECHANSTIC ASPECTS OF BIOSYNTHESIS OF SILVER NANOPARTICLES

  40. MECHANSTIC ASPECTS OF BIOSYNTHESIS OF SILVER NANOPARTICLES Naik et al. Nature Mater. 2002, 1, 169-172. Ohio, USA The silver-binding peptides from Pseudomonas stutzeriAG259 cells were obtained by using a combinatorial approach to identify these peptides from a phage display library of random peptides. The interaction of peptide with the metal clusters provides a chemically reducing environment around the cluster, thereby allowing further accelerated reduction of silver ions at the interface between peptide and metal.

  41. MECHANSTIC ASPECTS OF BIOSYNTHESIS OF SILVER NANOPARTICLES Si and Mandal, Chem Eur. J. 2007, 13, 3160-3168. Kolkata, India Similar results with tryptophan and gold Selvakannan et al. J. Colloids Interf. Sci. 2004, 269, 97-102 Bhattacharjee et al. J. Nanosci. Nanotechnol. 2005, 5, 1141-1147.

  42. MECHANSTIC ASPECTS OF BIOSYNTHESIS OF SILVER NANOPARTICLES Selvakannan et al. Langmuir, 2004, 20, 7825-7836. Pune, India Specific for Au Stacik et al. J. Mater Chem. 2005, 15, 749-753

  43. MECHANSTIC ASPECTS OF BIOSYNTHESIS OF SILVER NANOPARTICLES Fusarium oxysporum Durán et al. J. Nanobiotechnol. 2005. 3:8, 1-7. Campinas-SP-Brazil Durán et al. J. Biomed. Nanotechnol. 2007, 3, 203-208. Campinas, SP-Brazil Fusarium moniliforme was negative in quinone production

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