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The Atom. Review Class #1. Theories of the Atom. Greeks Matter is made up of tiny, discrete particles Fire, Earth, Wind, Water Boyle Found gold and silver as being elemental Dalton’s Theory All elements are composed of indivisible atoms All atoms of a given element are identical
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The Atom Review Class #1
Theories of the Atom • Greeks • Matter is made up of tiny, discrete particles • Fire, Earth, Wind, Water • Boyle • Found gold and silver as being elemental • Dalton’s Theory • All elements are composed of indivisible atoms • All atoms of a given element are identical • Atoms of different elements are different, that is, they have different masses • Compounds are formed by the combination of atoms of different elements
Experimental Parts of Atom – pg .3 • JJ. Thomson • Cathode ray tube to show smaller units make up atom • Light ray deflected in a magnetic field • Came up with idea of electrons • PLUM PUDDING MODEL • Nucleus • Rutherford • Bombarded atom with alpha particle • Alpha particle got deflected • Concluded atoms have a dense core – NUCLEUS • Because particles repelled, nucleus must be positive too • Also concluded atom is mostly empty space • Electrons are distributed in the empty space
Modern Atomic Model • Bohr • Dense nucleus • Electrons found in orbits • Electrons have required energy to keep them in orbit • Not too much or too little • Called this the planetary model • Wave Mechanical Model – modern model • Energy and matter can act as waves and particles • Solar panels • Dense positive center • Electrons are in “regions of probability”
Questions • RB pg. 4, 1-12
Structure of the Atom • Nucleus contains 2 types of particles • Neutrons and protons • This is where the mass comes from • Subatomic particles • Mass of a proton is found on 1st page of reference tables • 1 amu = mass of a proton = mass of 1 proton • Mass of electron is negligible
Subatomic particles • Sum of number of protons and neutrons equals the mass number • Found in the periodic table as atomic mass • Measured in amu (atomic mass units) NOT grams • If measured in grams would be atomic mass * mass of an atom
Isotopes • All type of element on periodic table have the same number of protons • Protons define the element • Neutrons can vary from atom to atom for 1 element • Same # protons but different number neutrons = isotopes • Examples: • Carbon – 12 = 6 protons and 6 neutrons • Carbon – 13 = 6 protons and _ neutrons
Atomic masses • Mass number for element must be integer • We can’t have part of a proton or neutron • Why are atomic masses of elements not integers? • Weighted atomic mass • The atomic mass is an average of all the different isotopes. • If have of the carbon isotopes were carbon 12 and half were carbon 13 • Weighted atomic mass would be 12.5 • Is this the weighted atomic mass for carbon? • Which isotope is more abundant?
Location of electrons • Found in space around a nucleus of an atom • Energy Levels • Orbitals in an atom form series of energy levels • S holds 2 electrons • P holds 6 electrons • D holds 10 electrons • This is where S, P, and D block names come from • Electrons can move between energy levels • You can walk up a set of stairs, takes a certain amount of energy • Certain amount of energy is needed for e- to jump between energy levels (it is quantized)
Ground vs excited state • Ground state – e- in lowest energy • Ground state is given in periodic table on ref. tables • If e- configuration doesn’t match ground state, it has to be excited state • Excited state • Electrons possess more energy than they would if they were in ground state • Spectral lines • Visible light that is emitted when electrons fall back to their ground state • Must first add energy to be excited – we can’t see this
Questions • RB pg. 7, 13-36