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Discover the potential of gas hydrate reservoirs for energy production and CO2 storage. Explore methods for methane extraction, storage of CO2 below seabed, and gas transport. Learn about the SUGAR Project and its innovative technologies.
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SUGAR Submarine Gas Hydrate Reservoirs: Exploration, Exploitation and Gas Transport CO2 CH4 Klaus Wallmann and Jörg Bialas
Hydrate Structure CH4× 5.7 H2O Water molecules Gas molecules
Methane Hydrate Stability Gas Hydrate Tishchenko, Hensen, Wallmann & Wong (2005) Buffett & Archer (2004)
Global Methane Hydrate Distribution Observations Source: Makogan et al., 2007
Global Methane Hydrate Distribution Modeling Source: Klauda & Sandler (2005)
Global Methane Hydrate Inventory in the Seabed Klau. (2005) Kven. (1999) Buff. (2004) Best estimate 3000 ± 2000 Gt C Mil. (2004)
Global Methane Hydrate Inventory Coal Oil Gas Hydrate Source: Energy Outlook 2007, Buffett & Archer (2004) Coal, oil, gas: reserves economically exploitable at current market prices Gas Hydrates: total marine inventory
Hydrate Exploitation • Methane gas may be produced from hydrate • deposits via: • Pressure reduction • Temperature increase • Addition of chemicals (incl. CO2)
Hydrate Exploitation Energy balance for Blake Ridge (Makogon et al. 2007) 2000 m water depth, two ~3 m thick hydrate layers ~40 % of the potential energy can be used for energy production ~60 % of the potential energy is lost during development, gas production, gas pressurization and transport Japanese Hydrate Exploitation Program Hydrate exploitation is economically feasible at an oil price of ~54 $/barrel
Gas Hydrates at the Chinese Continental Slope, South China Sea Source: N. Wu (2007, pers. comm.)
Gas Hydrates at the Indian Continental Slope Source: M. V. Lall (2007, pers. comm.)
Storage of CO2 below the Seabed SUGAR Safety, Costs
Phase Diagram of CO2 Risk of leakage decreases with water depth Self-sealing at >350 m
Natural Seepage at the Seafloor -Black Sea Gas Seeps- Source: Naudts et al. (2006)
The SUGAR Project • Funded by German Federal Ministries (BMWi, BMBF) • Funding period: June 2008 – May 2011 • Total funding: ~13 Mio € (incl. support by industries)
The SUGAR Project Prospection A: Exploration A1: Hydroacoustics A2: Geophysics A3: Autoclave-Drilling A4: Basin Modeling B: Exploitation and Transport B1: Reservoir Modeling B2: Laboratory Experiments B3: Gas Transport Exploration Quantification Exploitation/ CO2 Storage Pellet Transport
A1: Hydro-acoustic detection of hydrate deposits - Hydrate deposits are usually formed by gas bubble ascent - Multi-beam echo-sounders will be further developed and used for flare imaging and hydrate location Hydrate Ridge off Oregon
A2: Electro-magnetic imaging of hydrate deposits Joint inversion of seismic and electro-magnetic data
A3: Autoclave-drilling technology - develop autoclave technology for MeBo - develop tool for formation independent drilling
A4: Basin Modeling IFM-GEOMAR PetroMod3D (IES)
B1, B2: Exploitation Reservoir modeling and lab experiments
Hydrate Stability in Seawater (CO2 and CH4) Duan & Sun (2006) CO2 hydrates are thermodynamically more stable than CH4 hydrates
CH4(g)-Recovery from Hydrates Exposed to CO2 CO2(l) Kvamme et al. (2007) after 200 h in sandstone CO2(l) Hiromata et al. (1996) after 400 h CO2(g)/N2(g) Park et al. (2006) after 15 h CO2(g) Lee et al. (2003) after 5 h
B1, B2: Exploitation • Options • Addition of CO2(l), only • Addition of CO2(l) and heat from • - deep and warm formation waters (Schlumberger) • - surface water (UMSICHT, mega pump) • - in-situ methane burning (GFZ) • Addition of CO2(l) and polymers (BASF) • Addition of CO2(l) and other gases (IOW) • Exploitation may also be done in two steps • Step: Hydrate dissociation • Step: Injection of CO2(l) to refill the pore space • previously occupied by methane hydrates
B1, B2: Exploitation • Critical issues that need to be addressed: • Sluggish kinetics of gas swapping • Slope stability (avoid steep terrain) • Integrity of the unconsolidated cap sediments (overpressure < 10 bar) • Permeability of reservoir sediments (use sands) • Clogging by CO2 hydrate formation at the • injection point (add polymers or heat) • CO2 content of the produced methane gas • (avoid very high temperatures)
B3: Gas Transport Source: Gudmundsson (NTNU Trondheim), Aker Kvaerner, Mitsui Engineering & Shipbuilding Co.
B3: Gas Transport Source: Mitsui Engineering & Shipbuilding Co.
International cooperation • with India, Brasilia, China, Norway, South Korea, US • to apply the SUGAR exploration techniques • to perform a field production test during the second • SUGAR phase starting in summer 2011